In the current investigation, a vertically continuous casting technique was used to produce a ductile iron pipe. The ductile iron was austempered, and the tribological behavior of austempered ductile iron (ADI) was examined under various service conditions. The finding demonstrated that ADI’s tribological behaviors were significantly affected by normal loads and sliding speeds. Spheroidal graphite was preferential to be transferred from the matrix to the tribosurface in ADI under high normal loads, and high sliding speed accelerated the formation of the graphite lubricating layer on the tribosurface. Consequently, ADI’s friction coefficient dropped with the increase in normal load and sliding speed. When compared with the friction coefficient, the wear rate of ADI displayed a similar tendency in that it increased with an increase in normal load and reduced with an increase in sliding speed. The worn surface indicated that adhesive wear at low sliding speeds and abrasive wear at high sliding speeds were the primary wear mechanisms for ADI.