In this paper, MoS 2 nanosheets with an ultrathin structure were fabricated using a solvothermal method and further added into PAO oil, which was further combined with W-DLC coating to constitute a solid–liquid lubricating state. The influences of MoS 2 concentration, applied load and counter surfaces on the lubricating of the solid–liquid hybrid lubricating system were explored through a ball-on-disk tribometer. The friction results indicated that the steel/W-DLC and W-DLC/W-DLC tribopairs lubricated with ultrathin MoS 2 possessed better friction reduction and wear resistance behaviors in comparison to pure PAO oil. However, compared to the steel/steel couple case, the prepared MoS 2 nanosheets exhibited a more efficient lubricating effect for the W-DLC/W-DLC couple. The beneficial boundary lubricating impact of MoS 2 nanosheets on self-mated W-DLC coated rubbing surfaces could be attributed to the tribochemical reaction between MoS 2 and doping W element in DLC, resulting in a formation of a thin tribofilm at both counterparts. Meanwhile, the extent of graphitization of W-DLC film induced by friction was alleviated because of the lubrication and protection from the formation of MoS 2-based tribofilm at both counterparts.