This study investigates the role of sliding counterbodies, which significantly affect the wear properties and friction of nanocrystalline diamond (NCD) film. The bearing steel balls exhibit a high friction coefficient of 0.12, whereas a ceramic ball of Si3N4 achieves an ultralow friction coefficient of 0.06. The evolution of different friction coefficients with different counterbodies is associated with the formation of a tribolayer at the sliding interface. The decreased friction coefficient in NCD films sliding against Si3N4 ball is likely linked to the occurrence of lubricating nanostructures, especially the silica-like oxide compounds and graphite-like carbon phases. The findings of this study may provide new avenues for the design and development of wear-resistant and environment-friendly hard carbon films.