The tribological behavior depends significantly on friction heat under high sliding velocity. Many factors influence the conduction rate of friction heat, such as thermophysical properties of the pairs, the formation components of interface-film, environment mediums, etc. Through theoretical and experimental studies on surface temperature, the heat partition approaches have been applied to the pairs of M2 steel against GCr15 steel to compare and discuss their tribological behavior in dry sliding contact. The results indicate that the values of the contact pressure have little effect on the heat partition at a high sliding velocity of 40 m/s. Furthermore, the degree of correlation between the dynamic temperature and friction coefficient is obvious, and the correlation degree of parameters increases as the pressure grows. A close correlation exists among the temperatures measured from different points of the pin specimen. At last, X-ray diffraction analysis denotes that the carbides of secondary M6C are separated out during the process of friction.