The tribological behaviors of carbon block sliding against copper ring with and without electric current applied were investigated by using an advanced multifunctional friction and wear tester, and the electric-arc behaviors were analyzed in detail. The results show that the normal load is one of the main controlling factors for generation of electric arc during friction process with electric current applied. The strength of electric arc is enhanced with the decrease of normal loads and the increase of electric currents. The unstable friction process and the fluctuated dynamic friction coefficients are strongly dependent upon the electric arc. The wear volumes and the wear mechanism of carbon brush were affected by the electric arc obviously. As no electric arc occurs, no clear discrepancy of the wear volumes of the carbon samples with and without electric current applied could be detected. While the wear mechanisms are mainly mechanical wear. However, under the condition of the electric arc appearance, the wear volume of carbon with electric current applied increases much more rapidly than that without electric current applied and also increases obviously with the increase of electric current strengths and the decrease of normal loads. The wear mechanisms of carbon block are mainly electric arc ablation accompanying with adhesive wear and material transferring.