The cylinder liner-piston ring (CLPR) is one of the most critical frictional pair for energy conversion in diesel engines. In this study, two forms of surface texture were respectively prepared on the liner surface by laser processing, with the modified copper nanoparticles (CNP) applied as the lubricant additives. The reciprocating tribometer and accompanying tribological testing technologies were then used to explore the synergetic effects of surface textures and additives on the tribological properties of CLPR. The results show that the composite lubrication system exhibits good friction-reduction and wear-resistance as the appropriate texture was adopted. Additionally, the synergetic effects among the storage capability of textures and the self-repairing ability of CNP additives can explain the improvement mechanism of CLPR's tribological properties.