Recently, materials with superlubricity captured widespread attention on account of their great potential in energy savings and environmental protection. However, certain issues still remain to be solved for the traditional materials, such as the dependence on strict conditions and an unstable superlubricity state. Herein, a long-term stable superlubricity coating was prepared using a low-cost and simple method via an epoxy-based coating with polydimethylsiloxane (PDMS) brushes under silicone oil (SO) lubrication conditions. Compared with the pure epoxy resin matrix, the friction coefficient and wear track width of the superlubricity coating with the optimal amount of 6 wt % PDMS are reduced to 0.006 and 50.9 μm (reduced by 10-fold and 5.6-fold decrease, respectively). In addition, the coating can maintain a stable superlubricity state during a 5 h tribological test. The superlubricity of the coating results from the synergistic lubrication effect of the PDMS brush and SO. First, PDMS brushes with high-stretched conformation due to the swelling effect of the SO can significantly reduce friction. Second, a stable oil film is generated between the contact surfaces, which significantly improves the frictional performance. Moreover, the PDMS incorporated into the coating matrix, along with oil-swelling PDMS brushes on the surface, is highly beneficial for enhancing corrosion resistance of the epoxy resin matrix. Such an epoxy-based coating with long-term stable superlubricity is considered as a potential lubricating and protective surface for tribological components for long-term service.