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Oxidative Remote C-H Trifluoromethylation of Quinolineamides on the C5 Position with Iodobenzene Diacetate as the Oxidizing Agent

发表期刊: ASIAN JOURNAL OF ORGANIC CHEMISTRY

出版日期: 2016-06-01

在线发表日期: 2016-06

DOI: 10.1002/ajoc.201600128

作者: Wu, Zhaoyang; He, Yongqin; Ma, Chaowei; Zhou, Xiaoqiang; Liu, Xingxing; Li, Yamin; Hu, Ting; Wen, Ping; Huang, Guosheng;

A facile, metal-free protocol has been developed for the remote trifluoromethylation of 8-aminoquinoline scaffolds on the C5 position, which is difficult to functionalize. In this method, 8-aminoquinolineamides reacted with an inexpensive and commercially available CF3 source (Langlois reagent) to give a wide range of trifluoromethylated aminoquinolineamides.

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